Towards dipyrrins: oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes.
نویسندگان
چکیده
Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 5 شماره
صفحات -
تاریخ انتشار 2015